transition metal complexes
synthesis
spectral studies
azo dyes.
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Coupling reaction of 4-nitroaniline with 3-aminobenzoic acid provided the corresponding bidentate azo ligand. The prepared ligand was
identified by Microelemental Analysis, 1H-NMR, FT-IR, and UV-Vis spectroscopic techniques. Treatment of the prepared ligand with Y(III)
and La(III) metal ions in 1:3 M:L ratio in aqueous ethanol at optimum pH yielded a series of neutral complexes with the general formula of
[M(L)3]. The prepared complexes were characterized by flame atomic absorption, Elemental Analysis (C, H, N), FT-IR, and UV-Vis
spectroscopic methods, as well as conductivity measurements. The nature of the complexes formed were studied following the mole ratio
and continuous variation methods; Beer's law obeyed over a concentration range o
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