The Taxonomy of Political Discourse in Contemporary World in the Context of the Anthropocentric Paradigm

Mohammed Yassin Al-Barazanchi; Мохаммед Ясин Аль-Баразанчи

doi:10.18500/1817-7115-2019-19-4-384-389

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Publication Date

Mon Dec 02 2019

Journal Name

Izvestiya Of Saratov University. New Series. Series: Philology. Journalism

Volume

19

DOI

10.18500/1817-7115-2019-19-4-384-389

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The Taxonomy of Political Discourse in Contemporary World in the Context of the Anthropocentric Paradigm

discourse

political discourse

communicative space

modern politics

anthropocentric paradigm.

Mohammed Yassin Al-Barazanchi

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The article discusses political discourse as a communicative space of modern politics in the context of the anthropocentric paradigm. The following components of the political discourse have been outlined: the character of the subject and that of the addressee, genres of oral and written speech, the opposition of monologue and dialogue, the functions, the amount of information among the genres, the aim of speech.

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Publication Date

Sat Sep 30 2017

Journal Name

Al-khwarizmi Engineering Journal

Robot Arm Path Planning Using Modified Particle Swarm Optimization based on D* algorithm

D*

Free Cartesian Space

Path Planning

Particle Swarm Optimization (PSO)

Robot Arm.

Ahmed T.

Firas A.

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Abstract

Much attention has been paid for the use of robot arm in various applications. Therefore, the optimal path finding has a significant role to upgrade and guide the arm movement. The essential function of path planning is to create a path that satisfies the aims of motion including, averting obstacles collision, reducing time interval, decreasing the path traveling cost and satisfying the kinematics constraints. In this paper, the free Cartesian space map of 2-DOF arm is constructed to attain the joints variable at each point without collision. The D*algorithm and Euclidean distance are applied to obtain the exact and estimated distances to the goal respectively. The modified Particle Swarm Optimization al

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(10)

Publication Date

Sun Feb 25 2024

Journal Name

Baghdad Science Journal

SBOA: A Novel Heuristic Optimization Algorithm

autonomous learning

Evolutionary Computation

Heuristic optimization method

Single objective function

search space

Qi

Apri

WengHowe

Azland Mohd Zain

Hao long

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A new human-based heuristic optimization method, named the Snooker-Based Optimization Algorithm (SBOA), is introduced in this study. The inspiration for this method is drawn from the traits of sales elites—those qualities every salesperson aspires to possess. Typically, salespersons strive to enhance their skills through autonomous learning or by seeking guidance from others. Furthermore, they engage in regular communication with customers to gain approval for their products or services. Building upon this concept, SBOA aims to find the optimal solution within a given search space, traversing all positions to obtain all possible values. To assesses the feasibility and effectiveness of SBOA in comparison to other algorithms, we conducte

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(14)

Publication Date

Tue Jan 01 2019

Journal Name

Inorganica Chimica Acta

Synthesis, characterisation and electrochemistry of eight Fe coordination compounds containing substituted 2-(1-(4-R-phenyl-1H-1,2,3-triazol-4-yl)pyridine ligands, R = CH3, OCH3, COOH, F, Cl, CN, H and CF3.

(1

2

3-Triazol-4-yl)pyridine Redox potential Iron DFT

K.M.

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Eight different Dichloro(bis{2-[1-(4-R-phenyl)-1H-1,2,3-triazol-4-yl-κN3]pyridine-κN})iron(II) compounds, 2–9, have been synthesised and characterised, where group R=CH3 (L2), OCH3 (L3), COOH (L4), F (L5), Cl (L6), CN (L7), H (L8) and CF3 (L9). The single crystal X-ray structure was determined for the L3 which was complemented with Density Functional Theory calculations for all complexes. The structure exhibits a distorted octahedral geometry, with the two triazole ligands coordinated to the iron centre positioned in the equatorial plane and the two chloro atoms in the axial positions. The values of the FeII/III redox couple, observed at ca. −0.3 V versus Fc/ Fc+ for complexes 2–9, varied over a very small potential range of 0.05 V.

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Publication Date

Sat Sep 01 2018

Journal Name

Polyhedron

Novel dichloro (bis {2-[1-(4-methylphenyl)-1H-1, 2, 3-triazol-4-yl-κN3] pyridine-κN}) metal (II) coordination compounds of seven transition metals (Mn, Fe, Co, Ni, Cu, Zn and Cd)

The 1

3-dipolar cycloaddition “click” reaction between an azide and an alkyne to give a 1

2

3-triazole was reported by Huisgen in 1961 [1]. In 2002 the Copper(I)-catalyzed Azide-Alkyne Cycloaddition (CuAAC) to prepare a 1

2

3-triazole was reported [2]

[3]. The existence of relatively basic nitrogen atoms in the 1

2

3-triazole rings

and the possibility of introducing additional donor groups in the substituents (Fig. 1)

made the CuAAC “click” reaction an attractive method to prepare differently substituted 1

2

3-triazoles. These compounds have been used as ligands to coordinate to various metal ions that display a range of applications such as in electrochemical and photochemical studies

in supramolecular chemistry

magnetism

metal-ion sensing and catalysis [4]. The reasons for the success of the “click” reaction

is that it is easy to carry out and is widely applicable. It is not affected by a variety of functional groups

and can be carried out with a variety of Cu(I) catalysts and solvents

including aqueous conditions. The Cu(I) catalysts overcome the high activation energy barrier of the non-catalyzed Huisgen reaction by changing the mechanism of the reaction. A large variety of copper catalysts can be used for the CuAAC reaction

on condition that the maximum concentration of Cu(I) species is generated during the reaction. The pre-catalyst can be a Cu(II) salt (usually CuSO4) together with a reducing agent (often sodium ascorbate) or a Cu(I) compound in the presence of a base or amine ligand and a reducing agent to prevent oxidation to Cu(II). Some strong oxidising cupric salts or complexes such as Cu(OAc)2 also work. The solvent is very flexible from organic to aqueous

with the most commonly used combination water + an alcohol (t-BuOH

MeOH or EtOH). The key role of the solvent or solvent mixture is to solubilize the substrates and Cu(I) catalyst in order to ensure rapid reactions. Such aqueous conditions are very useful for biochemical conjugations

as well as for organic syntheses. We recently reported on the synthesis of a series of differently substituted 1

2

3-triazole chromophores

the substituted 2-(1-phenyl-1H-1

2

3-triazol-4-yl)pyridine ligands [5]

see Fig. 2 middle

with substituents R = H (L1)

CH3 (L2)

OCH3 (L3)

COOH

F

Cl

CN

CF3

O(CH2)3CH3 and N(CH3)2. These versatile ligands were found to coordinate to various first row transition metals

such as manganese

cobalt and nickel [6]. Here we extend the series to include more first row transition metal(II) coordination compounds

iron

copper and zinc

as well as a second row transition metal(II) coordination compound

cadmium

containing the 2-(1-(4-methyl-phenyl)-1H-1

2

3-triazol-1-yl)pyridine chromophore (Fig. 2 right with R = CH3). This series of seven novel coordination compounds is the first series of pyridyl-triazole based transition metal coordination compounds where seven different transition metals are coordinated to the same 1

2

3-triazole chromophore

namely 2-(1-(4-methyl-phenyl)-1H-1

2

3-triazol-1-yl)pyridine.

Kinaan M

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Publication Date

Mon Aug 12 2024

Journal Name

Научный Форум Филология ,искуссвоведение и культурология

СКРЫТЫЕ МИРЫ В РОМАНЕ МИХАИЛА БУЛГАКОВА «МАСТЕР И МАРГАРИТА» – АНАЛИТИЧЕСКОЕ ИССЛЕДОВАНИЕ

Ключевые слова: история создания

жанр

роман в романе

Москва 30-х годов

древний Ершалаим

три мира в романе

истина

совесть

любовь

творчество

трусость

бессмертие.

Самахер Хасан Давуд

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Аннотация. Роман «Мастер и Маргарита» – загадочное явление русской литературы. Статья побуждает задуматься над причинами столь широкой популярности главного романа жизни Михаила Булгакова. В ней рассмотрена история создания и публикации художественного произведения. Освещены тематика, жанр, особенности композиции романа, раскрыты образы героев. Структура романа замысловата и оригинальна. М. Булгаков

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Publication Date

Thu May 22 2025

Journal Name

Научный форум: Филология, искусствоведение и культурология

АНАЛИЗ УСТОЙЧИВЫХ ВЫРАЖЕНИЙ И ИХ РОЛИ В РУССКОМ ЯЗЫКЕ И КУЛЬТУРЕ

Нсрин

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Аннотация. Статья посвящена анализу устойчивых выражений (фразеологизмов, пословиц, поговорок, идиом) в русском языке и их роли в формировании языковой и культурной идентичности. Рассмат-риваются лингвистические характеристики, историко-культурный кон-текст, коммуникативные и прагматические функции, а также отражение русского менталитета и традиций. Особое внимание уделяется актуаль-ной проблеме транс

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Publication Date

Fri Dec 22 2023

Journal Name

Научный форум

ТЕМА МАЛЕНЬКОГО ЧЕЛОВЕКА В СБОРНИКЕ РАССКАЗОВ Л. ПЕТРУШЕВСКОЙ «ЖИЗНЬ -ЭТО ТЕАТР»

русская литература

современная проза

мра

Л. Петрушевская

рассказ

роман

образ героя

«маленький человек».

Mohammed

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Л. Петрушевская – одна из знаковых фигур современной российской прозы, однако ее творчество недостаточно изучено, работ по проблематике и поэтике ее произведений мало в российском и мировом литературоведении. Представляется, что такое невнимание к творчеству писательницы не обоснованно. Изучение произведений Л. Петрушевской позволит понять, как преломляются традиции классической русской литературы в

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Publication Date

Sat Dec 26 2020

Journal Name

International Journal Of Pharmaceutical Research

Complexes of Co(II), Cu(II), Ni(II), Pt(II) And Pd(II) with N 3 O-Chelating Ligand Incorporating Azo and Schiff Base Moieties: Synthesis, Spectroscopic, Thermal Decomposition, Theoretical Studies, and thermodynamic parameters

Alwan W.

...Show More Authors

Publication Date

Thu Mar 25 2021

Journal Name

International Journal Of Drug Delivery Technology

Synthesis, Structural Study, and Biological Activity Evaluation of VO(II), Mn(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II), and Hg(II) Complexes with New Schiff Base Ligand Derived from Pyrazine

bushra

Wurood

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New Schiff base [3-(3-acetylthioureido)pyrazine-2-carboxylic acid][L] has been prepared through 2 stages, the chloro acetyl chloride has been reacting with the ammonium thiocyanate in the initial phase for producing precursor [A], after that [A] has been reacting with the 3-amino pyrazine-2-carboxilic acid to provide a novel bidentate ligand [L], such ligand [L] has been reacting with certain metal ions in the Mn(II), VO(II), Ni(II), Co(II), Zn(II), Cu(II), Hg(II), and Cd(II) for providing series of new metal complexes regarding general molecular formula [M(L)2XY], in which; VO(II); X=SO4,Y=0, Co(II), Mn(II), Cu(II), Ni(II), Cd(II), Zn(II), and Hg(II); Y=Cl, X=Cl. Also, all the compounds were characterized through spectroscopic techniques [

Publication Date

Wed Feb 01 2023

Journal Name

Baghdad Science Journal

Synthesis, Theoretical Study, and Biological Evaluation of Some Metal Ions with Ligand "Methyl -6-[2-(4-Hydroxyphenyl) -2-((1-Phenylethylidene) Amino) Acetamido] -2,2-Dimethyl-5—Oxo-1-Thia-4-Azabicyclo [3.2.0] Heptane-3-Carboxyylate

Antimicrobial activity

DFT-PM3 Methods Theory

Schiff base complexes

Transition Metal ions

Sahar S.

Nafeesa J.

Zahraa. A.

...Show More Authors

Schiff base (methyl 6-(2- (4-hydroxyphenyl) -2- (1-phenyl ethyl ideneamino) acetamido) -3, 3-dimethyl-7-oxo-4-thia-1-azabicyclo[3.2.0] heptane-2-carboxylate)Co(II), Ni(II), Cu (II), Zn (II), and Hg(II)] ions were employed to make certain complexes. Metal analysis M percent, elemental chemical analysis (C.H.N.S), and other standard physico-chemical methods were used. Magnetic susceptibility, conductometric measurements, FT-IR and UV-visible Spectra were used to identified. Theoretical treatment of the generated complexes in the gas phase was performed using the (hyperchem-8.07) program for molecular mechanics and semi-empirical computations. The (PM3) approach was used to determine the heat of formation (ΔH˚f), binding energy (ΔEb), an

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