1
2
4-Triazole
Liquid crystals
Heterocyclic
Polymers
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Three series of monomers, polymers and thioester cyclic compounds containing 4H-1,2,4-triazol-3-thiol
moiety were synthesized and examined for their liquid crystalline properties. All monomers, polymers
and thioester compounds were characterized by elemental analysis and FTIR, 1
H-NMR and mass spectroscopy. The phase transition and mesomorphic properties were investigated by polarized optical microscope (POM) and differential scanning calorimetry (DSC). The monomer with terminal phenyl
substituent display dimorphism nematic and smectic A (SmA) mesophases. The corresponding polymers
derived from acrylic and phenyl acrylic acid monomers show nematic mesophase. The only thioester
cyclic compound derived from terephtaloyl chloride show nemati
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