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New metal ion complexes were synthesized with the general formula;
K[PtLCl4], [ReLCl4] and K[ML(Cl)2] where M = Pd(II), Cd(II), Zn(II) and Hg(II),
from the Azo ligand (HL) [2-Hydroxy-3-((5-mercapto-1,3,4-thiadiazol-2-yl)diazenyl)-
1-naphth aldehyde] (HL) the ligand was synthesized from (2-hydroxy-1-
naphthaldehyde) and (5-amino-1,3,4-thiadiazole-2-thiol). The ligand and its metal
complexes are characterized by phisco- chemical spectroscopic techniques (FT.IR,
UV-Vis and Mass spectra, elemental analysis, molar conductivity, Atomic
Absorption, Chloride contain and magnetic susceptibility). The spectral data suggest
that the (HL) behaves as a bidentate ligand in all complexes. These studies revealed
tetrahedral geometries for all metal complex
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