Abstract:
If we neglect the value of historical fashions as a source of inspiration for
contemporary fashion designers we will neglect a treasure of original designs.
In neglecting such a treasure how could we then know what is original. Today
the most famous fashion designers are often inspired, in the outwardly from
and internal lines of their fashions, by fashion designed during the ages of the
past.
Designers can find such fashions in books of history and museums. But
the historical ages are not equal in the fertility of the originality and novelty of
their fashions. Thus the contemporary designer may not find the old designs
inspiring so he invents them.
The researcher was keen in this paper to include all the basic concept of
the art of patchwork 3? and she referred to the historical background of this
art as well as its common tools . She also referred to the art of embroidery
and beadwork ... etc.
To connect the pieces with this classy art (patchwork)/
She discussed some modern producing techniques such as computer. (The
study ends with conclusion that suggests designs of the art of patchwork. the
paper included io suggested designs.)
The study includes inventive ideas. In order words producing great variety
from one idea or design with great intellectual and expensive freedom and
flexibility in prescribing the creative ideas that are original.
The paper is of tow parts. First is the theoretical part which is chapter two
of the study that tackles the studies related to the subject mentioned above.
The practical part includes a brief explanation of the steps of producing the
designs and their supplements. This proves that the art of patchwork is a
beautiful art, fit for artistic designs. Hence such designs are not less important
and beautiful than other designs that are not based on patchwork.
The researcher likes to bring the old to the era of development and
technology to make use of it and crystallize our artistic talents.
Therefore the study aims to preserve the art of patchwork with the addition of
modern and artistic touches with little cost as much as possible.
The purpose of my thesis is to synthesis two new bidentate ligands which were used to prepare series of metal complexes by reacting the ligands with (M+2 = Mn, Co, Ni, Cu, Cd and Hg) Succinyl chloride was used as starting material to synthesis two bidentate ligands (L1) and (L2) by reaction it with 4-chloroaniline (L1) and (4-aminoacetophenone) (L2) in dichloromethane as a solvent, that are: (L1) = N1,N4-bis (4-chloro phenyl ) succinamide (L2) =N1,N4-bis(4-acetylphenyl)succinamide The new ligands were characterize by using spectroscopic study (Fourier-transform infrared spectroscopy (FT-IR), electronic spectra ( UV-Vis) ,nuclear magnetic resonance(1H,13C-NMR), Mass spectra
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1-[4-(4-Acetyl-2-hydroxy-phenylazo)-phenyl]-ethanone (L1) and 1-[3-Hydroxy-4(4-nitro-phenylazo)-phenyl]-ethanone (L2) were readied by combination the diazonium salts of amines with 3-hydroxyacetophenone. (C.H.N) analyses, infrared spectra, UV–vis electronic absorption spectra, 1H and 13CNMR spectral mechanisms are use to identified of the ligands. Complexes of Ni+2 and Cu+2 were performed as well depicted. The formation of complexes has been identified by using atomic absorption of flame, elemental analysis, infrared spectra and UV-Vis spectral process as well conductivity and magnetic quantifications. Nature of compounds produced have been studied obeyed the mole ratio and continuous contrast methods, Beer's law followed during a concent
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