Background: Adjustment of any premature occlusal contact of any zirconia restoration requires its polishing or glazing in order to restore the smoothness of the restoration. The objective of this in vitro study was to evaluate the effects of different polishing systems and glazing on the surface roughness of full-contour zirconia. Material and methods: Forty disks (diameter: 8 mm, thickness: 6.4 mm) were prepared from pre-sintered full-contoured zirconia block; they were colored and sintered in a high-temperature furnace at 1500˚C for 8 hours. The specimens were then leveled and finished using grinding and polishing machine and adjusted using diamond disk. The specimens were then randomly divided into four groups (n=10), group I involves samples that were polished using (karat diamond polishing set, Vita zahnfabrik, Germany), group II involves samples that were polished with (zirconia polishing kit, SMEdent, Shanghai, China), group III involves samples that were polished with (OptraFine® diamond polishing system, Ivoclar Vivadent, Germany), while group IV involves samples that were glazed using glazing medium (VITA Akzent Glaze AKZ 25, Vita zahnfabrik, Germany). Surface roughness values (Ra) (in µm) of all the specimens were recorded at each stage of surface treatment of zirconia disks (leveling and finishing, adjustment of the samples and polishing / glazing) using surface roughness tester. Statistical analysis was carried out using one-way ANOVA and LSD tests. Results: The results showed that the glazing group recorded the lowest surface roughness mean value, followed by (OptraFine® polishing system), then (zirconia polishing kit) and finally (karat polishing set) which showed the highest mean of surface roughness. For all groups, there was a statistically very high significant difference of (Ra) value before and after adjustment of the samples. Moreover, there was a statistically very high significant difference in (Ra) value when comparing the adjusted samples with the polished and glazed ones. Karat polishing set group showed a statistically highly significant difference with zirconia polishing kit group (P<0.01). Both, karat polishing set and zirconia polishing kit groups showed a statistically very highly significant difference (P<0.001) with (OptraFine® polishing system) and glazing groups. On the other hand, no statistically significant difference was found between glazing and (OptraFine® polishing system) groups (P>0.05). Conclusions: Adjusting full-contour zirconia with diamond bur or disk resulted in a significant increase in (Ra) that necessitates its polishing or glazing to restore the surface smoothness. Furthermore, both glazing and OptraFine® polishing system provided the best surface smoothness, so glazing can be substituted with chairside polishing using OptraFine® polishing system.
اثناء تفاعل الديزنة تكونت صبغة أزو جديدة عن طريق تفاعل 3-امينوفينول مع 2,4,6-ثلاثي هيدروكسي اسيتوفينون . ثم تم تفاعل هذا الليكاند مع بعض ايونات العناصر الكروم والحديد الروديوم والروثينيوم بتكفؤهم الثلاثي والكوبلت الثنائي والموليبدينوم سداسي التكافؤ مكونة معقدات فلزية مختلفة بأشكال هندسية متعددة. تم ملاحظة تناسق مجموعة الازو مع ايونات العناصر من خلال ملاحظة ظهور حزم امتصاص الفلز مع النتروجين والاوكسجين ب
... Show MoreA new Schiff base [1-((2-(1H-indol-3-yl)ethylimino)methyl)naphthalene-2-ol] (HL) has been synthesized by condensing (2-hydroxy-1-naphthaldehyde) with (2-(1H-indol-3-yl)ethylamine). In turn, its transition metal complexes were prepared having the general formula; [Pt(IV)Cl2(L)2], [Re(V)Cl2(L)2]Cl and [Pd(L)2], 2K[M(II)Cl2(L)2] where M(II) = Co, Ni, Cu] are reported. Ligand as well as metal complexes are characterized by spectroscopic techniques such as FT-IR, UV-visible, 13C & 1H NMR, mass, elemental analysis. The results suggested that the ligand behaves like a bidentate ligand for all the synthesized complexes. On the other hand, theoretical studies of the ligand as well its metal complexes were conducted at gas phase using Hyp
... Show MoreThe ability of beans (Phaseolus vulgaris L.) to uptake three pharmaceuticals (diclofenac, mefenamic acid and metronidazole) from two types of soil (clay and sandy soil) was investigated in this study to explore the human exposure to these pharmaceuticals via the consumption of beans. A pot experiment was conducted with beans plants which were grown in two types of soil for six weeks under controlled conditions. During the experiment period, the soil pore water was collected weekly and the concentrations of the test compounds in soil pore water as well as in plant organs (roots, stems and leaves) were weekly determined.
The results showed that the studied pharmaceuticals were detected in all plant tissues; their concentration
Six house-hold Abyssinian pumps distributed in different villages of Mansoura (Mans-I, Mans-II and Mans-III) and Talkha (Talk-I, Talk-II and Talk-III) cities, Egypt, have been selected for regular seasonal water quality assessment during 2017. Water samples have been collected within the mid-periods of four seasons Standard assessment tools were employed for the integrated water quality assessment including Water Quality Index (WQI) and ISO standard algal toxicity test. WQI displayed remarkable local and seasonal variations with excellent (≥ 90) and good (70 - 89) only recorded for water samples collected from Mans-I pump located in sparsely populated area and far 50 meters only from the eastern (Damietta) branch of Nile River. WQI of
... Show MorePlantation of humic acid nanoparticles on the inert sand through simple impregnation to obtain the permeable reactive barrier (PRB) for treating of groundwater contaminated with copper and cadmium ions. The humic acid was extracted from sewage sludge which is byproduct of the wastewater treatment plant; so, this considers an application of sustainable development. Batch tests signified that the coated sand by humic acid (CSHA) had removal efficiencies exceeded 98 % at contact time, sorbent dosage, and initial pH of 1 h, 0.25 g/50 mL and 7, respectively for 10 mg/L initial concentration and 200 rpm agitation speed. Results proved that physicosorption was the predominant mechanism for metals-CSHA interaction because the sorption data followed
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