Background: This study was conducted to assess the effect of sonic activation and bulk placement of resin composite in comparison to horizontal incremental placement on the fracture resistance of weakened premolar teeth. Materials and method: Sixty sound human single-rooted maxillary premolars extracted for orthodontic purposes were used in this study. Teeth were divided into six groups of ten teeth each: Group 1 (sound unprepared teeth as a control group), Group 2 (teeth prepared with MOD cavity and left unrestored), Group 3 (restored with SonicFill™ composite), Group 4 (restored with Quixfil™ composite), Group 5 (restored with Tertic EvoCeram® Bulk Fill composite) and Group 6 (restored with Universal Tetric EvoCeram® composite using horizontal incremental layering technique). Standardized class II MOD cavity was prepared in all teeth except (group 1).After finishing the restorative procedure of each group according to the manufacturer's instructions, all teeth were stored in deionized distilled water in an incubator at 37°C for seven days.All specimens were subjected to compressive axial loading until fracturein a universal testingmachine.Specimens were examined by a stereomicroscope at a magnification of (20X) to evaluate the mode of fracture . Results: The results of this study revealed that the control group exhibited the highest fracture resistance compared to all prepared teeth groups (restored or unrestored) and the differences were statistically highly significant (P<0.01), except with group 3 (which was restored with SonicFill™ composite) where the difference was statistically significant only (P < 0.05).Additionally the results of this study revealed that the prepared unrestored teeth (Group 2) exhibited the lowest fracture resistance compared to all restored groups and the differences were statistically highly significant (P<0.01). Meanwhile, among the restored teeth groups, teeth restored with SonicFill™ composite (group 3) exhibited the highest fracture resistance as compared with all other restored groups and the difference was statistically highly significant (P<0.01). On the other hand, no statistically significant differences in fracture resistance were found among groups 4, 5 and 6, which were restored with Quixfil™ composite, Tetric EvoCeram® Bulk Fill composite and Universal Tetric EvoCeram® composite, respectively (P > 0.05). Group 3and Group 5 showed mostly mixed mode of failure, while Group 4 showed mostly adhesive mode of failure. On the other hand Group 6 teeth showed different modes of failure. Conclusions: SonicFill™ composite can be considered as a viable treatment modality for the restoration of weakened maxillary premolar teeth. On the other hand, the time-consuming incremental layering technique can be substituted with bulk filling, using bulk fill materials (Quixfil™ and Tetric EvoCeram® Bulk Fill) for reinforcement ofweakened maxillary premolars.
Some new complexes of 4-(5-(1,5-dimethyl-3-oxo-2-phenyl pyrazolidin-4- ylimino)-3,3-dimethyl cyclohexylideneamino) -1,5- dimethyl-2- phenyl -1H- pyrazol -3(2H) –one (L) with Mn(II), Fe(III), Co(II), Ni(II), Cu(II), Pd(II), Re(V) and Pt(IV) were prepared. The ligand and its metal complexes were characterized by phisco- chemical spectroscopic techniques. The spectral data were suggested that the (L) as a neutral tetradentate ligand is coordinated with the metal ions through two nitrogen and two oxygen atoms. These studies revealed Octahedral geometries for all metal complexes, except square planar for Pd(II) complex. Moreover, the thermodynamic activation parameters, such as ?E*, ?H, ?S, ?G and K are calculated from the TGA curves using Coa
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ne,؛Stability constants were determined for complexes of amino acids : L-leuc tryptophane and Aspartic acid with thorium (IV ) and uranyle ( U02++) ions at ؛ serine
Oscillation criteria are obtained for all solutions of the first-order linear delay differential equations with positive and negative coefficients where we established some sufficient conditions so that every solution of (1.1) oscillate. This paper generalized the results in [11]. Some examples are considered to illustrate our main results.
2-(2-amino-5-nitro-phenylazo),-phenol was ready by grouping the diazonium salt of 2-aminophenol with 4-nitroaniline.Thegeometry of azo ligand(HL)was resolved on the origin of (C.H.N) analysis,1H and 13CNMR spectra, infrared spectra and UV–vis electronic absorption spectra. Dealing with the azo ligand produced with Rh+3 and La+3ataqueous ethanol for a 1:3 metal: ligand rate, and in perfect ph. The formation for compounds have been described by utilizing flame atomic, absorption,(C.H.N),Analyses, conductivity, infrared spectra and UV–vis spectral procedures. Nature in the produced compounds, have been studied, obey the ratio of mole and continuous, variance, manners, Beer's law, yielded up a concentration, rate (1×10-4- 3×10-4M),. High
... Show MoreIn this work, polyvinylpyrrolidone (PVP), Multi-walled carbon nanotubes (MWCNTs) nanocomposite was prepared and hybrid with Graphene (Gr) by casting method. The morphological and optical properties were investigated. Fourier Transformer-Infrared (FT-IR) indicates the presence of primary distinctive peaks belonging to vibration groups that describe the prepared samples. Scanning Electron Microscopy (SEM) images showed a uniform dispersion of graphene within the PVP-MWCNT nanocomposite. The results of the optical study show decrease in the energy gap with increasing MWCNT and graphene concentration. The absorption coefficient spectra indicate the presence of two absorption peaks at 282 and 287 nm attributed to the π-π* electronic tr
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