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Reaction of  p-fluoro benzoic acid with the thiosemicarbazide and salcialdehyde gave the new bidentate
ligand .The prepared ligand Identified by FT-I.R and U.V-Visible spectcopic technique .Treatment of the
prepared   ligand   with following metal ions  M=Tb(III),Eu(III),Nd(III) and La(III) ,in ethanol
with a (1:1) M:L ratio and at pH=7 yielded series of neutral complexes as the general formula  [M
LCl (H O ]. The prepared complexes were characterized using (FT-IR, UV-Vis)Â spectra , melting point, molar
conductivity measurements . chloride ion content were also evolution by (mhor method) . The proposed structure
of the complexes using program , chem office 3D(2004) .