The aim of this investigation is to determine how different weight percentages of alumina nanoparticles, including 0.02, 0.04, and 0.06 percent wt, affect the physical characteristics of Poly Acrylamide (PAAM). Using a hot plate magnetic stirrer, 10 g of poly acrylamide powder was dissolved in 90 g of di-ionized distillate water for 4 hours to produce PAAM with a concentration of 0.11 g/ml. Four sections of the resulting solution, each with a volume of 20 ml, were created. Each solution was added independently with alumina nanoparticles in different ratios 0.0, 0.02, 0.04, and 0.06 to create four nano fluid solutions with different alumina nanoparticle contents based on each weight percent. The hand casting process for nanocomposites samples, which entailed pouring the prepared solution into an appropriate plastic mold, allowing it to cure for 24 hours, and then cutting the resulting thin film according to each test, was used to create the nano composited membranes. The tensile test was used to study tensile strength, Young's modulus, elongation, and toughness. Additionally, a test using Fourier transition infrared radiation (FTIR) was conducted to examine the chemical and physical connections between polyacrylamide and alumina nanoparticles. The morphology of the materials was examined using scan electron microscopy. The contact angles of samples were tested to limit the hydrophilicity behavior of these samples. To control the hydrophilicity behavior of these samples, the contact angles of the samples were evaluated. The results showed that including alumina nanoparticles into the PAAM matrix improves the mechanical characteristics of the resulting nanocomposites. Tensile strength increases from 1 GPa to 2.5 GPa with an increase in alumina nanoparticle content from 0 to 0.06 percent wt. For the same prior ratios, Young's modulus likewise increased, rising from 1.3 to 2 GPa. For the higher weight ratio of alumina nanoparticles (0.04 percent wt), toughness rises to 240 J/cm2. On the other hand, the addition of alumina nanoparticles increased the PAAM surface's contact angle from 55 degrees to 67 degrees, and it exhibited hydrophilic behavior
Background: This study was performed to compare the marginal fit changes and facture resistance of metal ceramic crowns constructed from Ceramill Sintron metal coping veneered with three different porcelain veneering materials (Vita Master Koromikos VMK, Willi Geller Creation CC and GC initial MC), also to evaluate the influence of thermocycling on load at fracture. Materials and Methods: Master brass die was scanned ,then metal coping was designed and milled from Ceramill Sintron blank to get 60 metal copings, then divided randomly into three groups(20 sample), then veneered with porcelain: VITA, Creation or GC. The marginal gaps were measured before and after porcelain veneering then marginal fit changes was calculated. Fracture resist
... Show MoreWe present a simple model of charge transfer current through sensitizer N3 molecule contact to TiO2 and ZnO semiconductors to calculate the charge transfer current. The model underlying depends on the fundamental parameters of the charge transfer reaction and it is based on the quantum transition theory approach. A transition energy, driving energy and potential barrier have been taken into account charge transfer current at N3 / TiO2 and N3 / ZnO devices with wide polarity solvents Acetic acid, 2-Methoxyethanol, 1-Butanol, Methyl alcohol, chloroform, N,N-Dimethylacetamide and Ethyl alcohol via the quantum donor-acceptor system.The effects of the transition energy and potential barrier are computed and discussion on charge transfer current.
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