A new ligand [ 2-chloro-N- (1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro -1H-pyrazol- 4- ylcarbamothioyl)acetamide](L) was synthesized by reacting the Chloro acetyl isothiocyanate with 4-aminoantipyrine,The ligand was characterized by(C HNS) elemental microanalysis and the spectral measurements including Uv-Vis ,IR ,1H and13C NMR spectra, some transition metals complex of this ligand were prepared and characterized by Uv-Vis, FT-IR spectra, conductivity measurements, magnetic susceptibility and atomic absorption. From the obtained results the molecular formula of all prepared complexes were [M(L)2(H2O)2]Cl2 (M+2 =Mn, Co, Ni, Cu, Zn, Cd and Hg),the proposed geometrical structure for all complexes were octahedra

Concrete structures are exposed to aggressive environmental conditions that lead to corrosion of the embedded reinforcement and pre-stressing steel. Consequently, the safety of concrete structures may be compromised, and this requires a significant budgets to repair and maintain critical infrastructure. Prediction of structural safety can lead to significant reductions in maintenance costs by maximizing the impact of investments. The aim of this paper is to establish a framework to assess the reliability of existing post-tensioned concrete bridges. A time-dependent reliability analysis of an existing post-tensioned involving the assessment of Ynys-y-Gwas bridge has been presented in this study. The main cause of failure of this bridge was c

ABSTRACT. 4-Sulfosalicylic acid (SSA) was used as a ligand to prepare new triphenyltin and dimethyl-tin complexes by condensation with the corresponding organotin chloride salts. The complexes were identified by different techniques, such as infrared spectra (tin and proton), magnetic resonance, and elemental analyses. The 119Sn-NMR was studied to determine the prepared complexes' geometrical shape. Two methods examined the antioxidant activity of (SSA) and prepared complexes; Free radical scavenging activity (DPPH) and CUPRRAC methods. Tri and di-tin complexes gave high percentage inhibition than ligands with both methods due to tin moiety; the triphenyltin carboxylate complex was the best compared with the others. Also, antibacter

This work dealt with separation of naphthenic hydrocarbons from non-naphthenic hydrocarbons and in particular concerns an improved process for increasing the naphthenes concentration in naphtha, The separation was examined using adsorption by Y and  B zeolite in a fixed bed process. The concentration of naphthenes in the influent and effluent streams was determined using PONA classification. The effect of different operating variables such as feed flow rate (2- 4 L/hr); bed length (50 - 80 cm) on the adsorption capacity of Y and  zeolite was studied. Increasing the bed length lead to increase the naphthenes concentration, and increasing the flow rate lead to decrease in the concentration of naphthenes, It was found that the decrease

In the Iraqi educational context, the academic presentation of learning and teaching Spanish faces several challenges due to the lack of updated teach-ing resources, absence of new teaching and learning methodologies, and in-adequate infrastructure to accommodate students in their study locations, among other issues. Given this comprehensive landscape, this article pro-poses a documentary analysis investigating the potential advantages of im-plementing self-regulation as a strategy for teaching and learning Spanish in the Iraqi educational setting. Accessing clarification of some fundamental concepts, self-regulation can be understood as the control each individual can exert over their thoughts, actions, emotions, and strategies,

The essential objective of this study presents a analyzes of the combination of reality and fantasy in three dramas of Spanish author Alejandro Casona. "Trees die standing" (premiered in Buenos Aires in 1949), “Prohibited suicide in spring” (premiered in Mexico in 1937) and "The boat without fisherman" (premiered in Buenos Aires in 1945).

  The first part is an introduction about the biography of Spanish author Alejandro Casona that will allow us to understand some peculiarities of his work in relation to the social historical context of his time.

 In the second part of this study we have analyzed elements of reality and fantasy in the th

رضًٍ ْزا انجذث رذضٛش ٔرشخٛض انهٛكبَذ انجذٚذ [KL [: - رفبػم ٍي ذضشًان K [4-{N-(5-methylisoxazol-3-yl) sulfamyl} phenyl carbamodithioate] عهفبيٛثٕكغبصٔل يغ ثُبئٙ كجشٚزٛذ انكبسثٌٕ ثٕجٕد ْٛذسٔكغٛذ انجٕربعٕٛو رذذ انزظؼٛذ االسجبػٙ ) نًذح اسثغ عبػبد ( ٔثئعزؼًبل انًٛثبَٕل كًزٚت نُٛزج انهٛكبَذ انًزكٕس اَفب رى رشخٛض انهٛكبَذ انًذضش ثبعزؼًبل طٛف االشؼخ رذذ انذًشاء ، ً طٛف االشؼخ فٕق انجُفغجٛخ - انًشئٛخ ، طٛف انشٍَٛ انُٕ٘ٔ انًغُبطٛغٙ نهجشٔرٌٕ أنهكبس