Two Schiff bases, namely, 3-(benzylidene amino) -2-thioxo-6-methyl 2,5-dihydropyrimidine-4(3H)-one (LS])and 3-(benzylidene amino)-6-methyl pyrimidine 4(3H, 5H)-dione(LA)as chelating ligands), were used to prepare some complexes of Cr(III), La(III), and Ce(III)] ions. Standard physico-chemical procedures including metal analysis M%, element microanalysis (C.H.N.S) , magnetic susceptibility, conductometric measurements, FT-IR and UV-visible Spectra were used to identify Metal (III) complexes and Schiff bases (LS) and (LA). According to findings, a [Cr(III) complex] showed six coordinated octahedral geometry, while [La(III), and Ce(III) complexes]were structured with coordination number seven. Schiff's bases and mineral complexes were examined in vitro to investigate potential inhibition against Gram-positive bacteria such as Pseudonomous aerugionosa and Gram-negative bacteria such as Staphylococcus aureus. The low concentration for inhibition has been also determined by studying the minimal inhibitory concentrations MIC .Antibiotics (Ampicillin, Amoxicillin) have been chosen to contrast their activity. Furthermore, Anti-fungal activity against two types of fungi ʺAspergillus flavusʺ and ʺPenicillum Spp.ʺ was studied for these compounds. The results of the antibacterial activity were better compared to the standard drugs.
The snthesis and characterization of cobalt(II), nickel(II), copper(II) and zinc(II) complexes of azo ligand 4-[(5-acetyl-2-aminophenyl)- diazenyl]-1,5-dimethyl-2-phenyl-1H-pyrazol-3(2H)-one derived from 4-aminoantipyrine and 4-aminoacetophenone are reported. The nature of the compounds have been studied followed by mole ratio and methods of continuous contrast, Beer′s law followed during a condensation rate (1 × 10-4 – 3 × 10-4 M). The analytical data showed that all the complexes are in 1:2 metal-ligand ratio. An octahedral geometry have been suggested for all the compounds and biological studies of all the complexes were evaluated against different types of antimicrobial strains.
Pulsed liquid laser ablation is considered a green method for the synthesis of nanostructures because there are no byproducts formed after the ablation. In this paper, a fiber laser of wavelength 1.064 µm, peak power of 1 mJ, pulse duration of 120 ns, and repetition rate of 20 kHz, was used to produce carbon nanostructures including carbon nanospheres and carbon nanorods from the ablation of asphalt in ethanol at ablation speeds of (100, 75, 50, 10 mm/s). The morphology, composition and optical properties of the synthesized samples were studied experimentally using FESEM, HRTEM, EDS, and UV-vis spectrophotometer. Results showed that the band gap energy decreased with decreasing the ablation speed (increasing the ablation time), the mi
... Show Moreدرست بعض خصائص عامل الالتصاق (تلزن) بكتريا Enterococcus faecalis EM1 مع خميرةSaccharomyces cerevisiae , اذ تم تعريض خلايا البكتريا لظروف مختلفة تضمنت درجات حرارة وارقام هيدروجينية وتراكيز من كلوريد الصديوم ومضادات حياة مختلفة.
The work involves synthesis of new Schiff bases ([V] a, b and [VI] a, b), pyrazoles [VII] a, b and pyrazolines [VIII] a, b derivatives containing isoxazoline unit starting with chalcones. 4-bromoacetophenone was reacted with 4-hydroxybenzaldehyde or 4-hydroxyacetophenone was reacted with 4-bromobenzaldehyde in basic medium to give chalcone by Claisen-Schemidt reaction. The chalcons [I] a, b was reacted with hydroxylamine hydrochloride to form isoxazolines [II] a, b. which were reacted with ethyl chloro acetate in basic medium to get ester compounds [III] a, b. The condensation new ester [III] a, b with hydrazine hydrate80% yieldedacid hydrazide [IV] a, b. The later compound refluxing with 4-substituted benzaldehyde in dry benzene to give Sc
... Show MoreI've been in this work to prepare some complexes containing mixed Kandat with some transitional elements which new complexes according to the best of our knowledge and to refer to the information from the Internet until I have been studying this diagnosis Aalmakdat
L'œuvre de fiction la plus ancienne qui nous soit restée, est aussi bien la première jamais écrite. L'épopée de Gilgamesh a été composée à l'aube de la civilisation mésopotamienne. Gilgamesh était le cinquième souverain après le déluge.
Sous son règne, trois millénaires environ avant Jésus-Christ, les Urukiens s’emparèrent des cités voisines, et formèrent ainsi ce que nous appellerions une petite nation. Pendant plus de deux mille ans, les civilisations du Proche-Orient ont fait de Gilgamesh leur héros épique. Il existe des
... Show MoreEl Quijote no es sólo una novela para leer. Es también un acontecimiento
celebrado en todos los medios de expresión artísticos y literarios: la poesía, el
ensayo, la ilustración, la pintura, la escultura, las artes decorativas, la iconografía
popular, el humor.
Las figuras de Don Quijote y Sancho Panza, como arquetipos que entran a
formar parte de la vida cotidiana de las gentes, aparecen representados en miles de
cuadros, grabados, esculturas y tapices. El cine, el ballet y la ópera han sido y
siguen siendo espectáculos de acogida para nuestros personales. No faltan las obras
musicales que se inspiran en ellos y sus figuras aparecen representadas en objetos
tan variados como utensilios de cocina, vest