The zirconia ceramic restoration (ZCR) is used as substitutes for the metal-ceramic restoration. Clinical studies demonstrating of ZCRs showed a high fracture incidence of veneering layer than metal-ceramic restorations. This attributed to the low bond strength of zirconia to veneering ceramic as a result of lacking of glass content in its matrix. Surface treatment was proposed to improve the bonding strength between zirconia and veneering ceramic. Several studies revealed that some treatment such as airborne particle abrasion (APA) is responsible for generating chipping of veneering ceramic. The study aimed to develop a new zirconia coatings to increase bonding strength between zirconia substrate and veneering porcelain. Three groups of 150 zirconia specimens (discs, rods and crowns) were divided according to the type of surface treatments; Group M1 designated unsintered zirconia specimens coated with a mixture of glaze porcelain powder and partially-sintered zirconia powder prepared at 1100 °C with two particle sizes; A (26 ± 0.3 μm) and size B (47 ± 0.5 μm), group M2 was coated with mixture of ceramic liner paste and same selected particle sizes of partially-sintered zirconia powders. The coated groups (M1 and M2) subdivided according to powder sizes into M1A, M1B, M2A and M2B. APA group (as control) of sintered zirconia specimens abraded with 50 μm aluminium oxide powder. Surface area roughness (Sa) was measured by surface texture analyser. Surface morphology and elemental composition were analysed by scanning electron microscope (SEM). Crystallographic phases were identified by X-ray diffraction (XRD). The coefficient of thermal expansion (CTE) was assessed by a thermomechanical analyser. For shear bond strength (SBS) test was evaluated by a universal testing machine (UTM). The fracture strength (FS) test prepared and measured by Cercon CAD/CAM system and UTM. Fractographic analysis for SBS and FS were examined by a stereomicroscope and SEM. For each test and measurement, 10 specimens were used per group. Finite element analysis (FEA) was used to simulate and predict the iv stress distributions of the static oblique load in coated and non-coated zirconia crown models. The collected data were analysed by one-way ANOVA and Tukey HSD test at (P<0.05). Surface roughness results showed significant differences among all groups (P<0.000). The M1B group exhibited a higher Sa value (10.33 ± 0.59 μm) among the tested groups. XRD analysis showed tetragonal and monoclinic phases in the control group while only tetragonal was detected in the coated groups. The SBS values for coated groups were higher than the control group. The M1B group showed higher and significant differences in SBS value (37.54 ± 4.38 MPa) among other tested groups (P<0.05). The FS test indicated that coated M1B group (647.92 ± 97.33 N) higher than the other groups (P<0.00). FEA showed the coated crown models have lower stress level than the non-coated model. The new coating (M1B) by airbrush spray technique considered as an alternative way to APA treatment to improve the bond strength of zirconia substrate to veneering ceramic and indicating as an applicable surface treatment for improving the clinical performance of the coated ZCR.
The performance and lifetime of the flexible asphalt pavement are mainly dependent on the interfacial bond strength between layer courses. To enhance the bond between layers, adhesive materials, such as tack coats, are used. The tack coat itself is a bituminous material, which is applied on an existing relatively non-absorbent surface to ensure a strong bond between the old and newly paved layer. The primary objective of this study was to evaluate the effects of various types of tack coat materials on interlayer bond strength and to determine the optimal application rate for each type. The tack coat types used in this paper were RC-70, RC-250, and CSS-1h. Both laboratory-prepared and field-constructed hot mix asphalt concrete pavements usin
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SIFCON is characterized as a construction material of high ductility and very high strength. It is suitable for concrete structures used for special applications. However, the density of SIFCON is much higher than that of Fiber Reinforced Concrete (FRC) due to the need for a large amount of high-density steel fibers. This work examines the split tensile behavior of modified weight slurry infiltrated fiber concrete utilizing a mixture of two types of fibers, steel fiber, and polyolefin fiber. For the investigation, 30 cylinders and 15 cubes were poured. The used volume fraction (V.F) is (6 %) and the use of five series once as each type separately and once a hybrid in proportions of 2/3 polyolefin with 1/3 steel fiber and
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Previous experimental studies have suggested that hot mixed asphalt (HMA) concrete using hydrated lime (HL) to partially replace the conventional limestone dust filler at 2.5% by the total weight of all aggregates showed an optimum improvement on several key mechanical properties, fatigue life span and moisture susceptibility. However, so far, the knowledge of the thermal response of the modified asphalt concrete and thermal influence on the durability of the pavement constructed are still relatively limited but important to inform pavement design. This paper, at first, reports an experimental study of the tensile fatigue life of HMA concrete mixes designed for wearing layer application. Tests were conducted under three different temperatur
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The complexes of the 2-hydroxy-4-Nitro phenyl piperonalidene with metal ions Cr(III), Ni(II), Pt(IV) and Zn(II) were prepared in ethanolic solution. These complexes were characterized by spectroscopic methods, conductivity, metal analyses and magnetic moment measurements. The nature of the complexes formed in ethanolic solution was study following the molar ratio method. From the spectral studies, monomer structures proposed for the nickel (II) and Zinc (II) complexes while dimeric structures for the chromium (III) and platinum (IV) were proposed. Octahedral geometry was suggested for all prepared complexes except zinc (II) has tetrahedral geometry, Structural geometries of these compounds were also suggested in gas phase by using
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: The aim of this research is to investigate the impact of Woods ' strategy in collecting second graders average for physics. To achieve the objective researcher coined the following hypothesis: there was no statistically significant difference at a level (0.05) between the average grades of the experimental group students studying physics as Woods and strategy between the average control group students who are studying the same article in the regular way. Test collection. Search sample amounted to (83) students and (42) students for the experimental group, and (41) students for the control group. Students were subjected to test experiment is composed of (30) after the completion of the experiment. And use appropriate statistical methods re
... Show MoreThe nanocomposite on the base of synthesis Copper iodide
nanoparticles and polyvinyl alcohol (PVA/CuI) with different
concentration of CuI were obtained using casting technique.
PVA/CuI polymer composite samples have been prepared and
subjected to characterizations using FTIR spectroscopy, The FTIR
spectral analysis shows remarkable variation of the absorption peak
positions with increasing CuI concentration. The obtained results by
X-ray diffraction indicated the formation of cubic CuI particles. The
effects of CuI concentrations on the optical properties of the PVA
films were studied in the region of wavelength, (190-1100) nm.
From the derivation of Tauc's relation it was found that the direct
allowed t
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This work has been done with using of epoxy resin mixed with Granite powder were weighted by percent volume (5,10,15, and 20)%and then mixed with epoxy polymer to compose polymer composite. Hand lay-up technique is used in fabrication of the composite samples. Hardness test was carried out for the proper samples in both normal condition and after immersion in HCL (1 M and 2 M) solutions for periods ranging up to 10 weeks. After comparing the results between the polymer and their composite, the hardness increased with increasing Granite weight percent, it was found that Hardness were greater for the composites before immersion compared with their values after immersion.