اثناء تفاعل الديزنة تكونت صبغة أزو جديدة عن طريق تفاعل 3-امينوفينول مع 2,4,6-ثلاثي هيدروكسي اسيتوفينون . ثم تم تفاعل هذا الليكاند مع بعض ايونات العناصر الكروم والحديد الروديوم والروثينيوم بتكفؤهم الثلاثي والكوبلت الثنائي والموليبدينوم سداسي التكافؤ مكونة معقدات فلزية مختلفة بأشكال هندسية متعددة. تم ملاحظة تناسق مجموعة الازو مع ايونات العناصر من خلال ملاحظة ظهور حزم امتصاص الفلز مع النتروجين والاوكسجين بتقنية مطيافية الاشعة تحت الحمراءمشيرة إلى ارتباط النيتروجين والأكسجين مباشرة مع الفلز .تم تعيين الاوزان الجزيئية لليكاند ومعقداته بأستخدام مطيافية الكتلة وكذلك تم عمل تحليل للعناصر. تم قياس حزم امتصاص الاطياف الالكترونية لتحديد الشكل الهندسي للمعقدات , اضافة الى ذلك تم تحديد استقرارية المركبات من حيث احتواءها على جزيئات الماء من عدمه باستخدام تقنيتي المسح الحراري التفاضلي التحليل الحراري الوزني تم قياس تأثير المعقدات كمضادات اكسدة اتجاه 2,2-داي فينل بكريل هيدرازيل (DPPH) وهو عبارة عن جذر حر مستقر الذي يتم استخدامه لمعرفة فعالية كسح الجذور الحرة لنواع الاوكسجين النشطة ولوحظ التالي (H4L > Ascorbic acid > Mo-Complex > Fe-Complex > Cr-Complex > Rh-Complex > Ru-Complex) خلال ثلاثون دقيقة . اختبار DPPH قام باختزال الالكترون المنفرد لذرة النتروجين عن طريق استلام ذرة هيدروجين من المعقدات المضادة للكسدة لتكوين الهيدرازين المقابل . نتيجة الفحص تراوحت مابين قيم تثبيط لمركبات نشطة وغير نشطة تم ادراجها في البحث.
In this effort, we define a new class of fractional analytic functions containing functional parameters in the open unit disk. By employing this class, we introduce two types of fractional operators, differential and integral. The fractional differential operator is considered to be in the sense of Ruscheweyh differential operator, while the fractional integral operator is in the sense of Noor integral. The boundedness and compactness in a complex Banach space are discussed. Other studies are illustrated in the sequel.
A novel demountable shear connector for precast steel-concrete composite bridges is presented. The connector uses high-strength steel bolts, which are fastened to the top flange of the steel beam with the aid of a special locking nut configuration that prevents bolts from slipping within their holes. Moreover, the connector promotes accelerated construction and overcomes the typical construction tolerance issues of precast structures. Most importantly, the connector allows bridge disassembly. Therefore, it can address different bridge deterioration scenarios with minimum disturbance to traffic flow including the following: (1) precast deck panels can be rapidly uplifted and replaced; (2) connectors can be rapidly removed and replaced; and (
... Show MoreSoil improvement has developed as a realistic solution for enhancing soil properties so that structures can be constructed to meet project engineering requirements due to the limited availability of construction land in urban centers. The jet grouting method for soil improvement is a novel geotechnical alternative for problematic soils for which conventional foundation designs cannot provide acceptable and lasting solutions. The paper's methodology was based on constructing pile models using a low-pressure injection laboratory setup built and made locally to simulate the operation of field equipment. The setup design was based on previous research that systematically conducted unconfined compression testing (U.C.Ts.). Th
... Show MoreTo evaluate the efficiency and effectiveness of three minimally invasive (MI) techniques in removing deep dentin carious lesions. Forty extracted carious molars were treated by conventional rotary excavation (control), chemomechanical caries removal agent (Brix 3000), ultrasonic abrasion (WOODPECKER, GUILIN, China); and Er, Cr: YSGG laser ablation (BIOLASE San Clemente, CA, USA). The assessments include; the excavation time, DIAGNOdent pen, Raman spectroscopy, Vickers microhardness, and scanning electron microscope combined with energy dispersive X-ray spectroscopy (SEM–EDX). The rotary method recorded the shortest excavation time (p < 0.001), Brix 3000 gel was the slowest. DIAGNOdent pen va
Background/Aims: The nano-method has been used as a technique for creating novel, non-traditional antimicrobial agents. This effective method for treating infectious diseases has many advantages over conventional antibiotics, including increased efficacy against species that have developed drug resistance, and the ability to circumvent the development of resistance that disrupts a number of biological pathways. As a result, the objective of this study was to synthesize and characterize silver nanoparticles using phenolic compounds obtained from Camellia sinensis. The nanoparticles were then used as antibacterial agents on the multidrug resistant Staphylococcus aureus, as well as, biofilm formation mechanism were also investigated. M
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