The ligand 4-(2-aminmo-5-nitro-phenylazo)-1,5-dimethyl-2-phenyl-1,2-dihydro-pyrazol-3-one derived from 4-aminoantipyrine and 4-nitroaniline was synthesized. The synthesized ligand was characterized by 1HNMR, FT-IR, UV-Vis spectra and (C.H.N) analysis. Complexes of (YIII and LaIII ) with the ligand were prepared in aqueous ethanol with a 1:2 M:L ratio and at optimum pH. The prepared complexes were characterized by using flame atomic absorption, FT-IR, UV-Vis spectra,(C.H.N) analysis and conductivity measurement. The stoichiometry of complexes was studied by the mole ratio and job methods. A concentration range (1×10-4 - 3×10-4 M) obeyed Beer's law, the complex solutions show high values of molar absorption. On the basis of physicochemical data octahedral geometries were attributed for the complexes. All prepared compounds exhibited good antibacterial activity, the ligand and their complexes were application to cotton fabric and study of the detergent fastness.
Synthesis, Spectral and Dyeing Performance Studies of 4-(2-Aminmo-5-nitro-phenylazo)-1,5-dimethyl-2-phenyl-1,2-dihydro-pyrazol-3-one Complexes with Some Metal Ions
Complexes
Synthesis of Dyes
Biological Activity
Publication Date
Mon Jan 01 2024
Journal Name
Anais Da Academia Brasileira De Ciências
Morphological study for Accipitrid birds (Accipitridforms, Accipitridae) in Iraq; part two
A part two of Accipitridae Family members that belong to three genera:
Circus
Gyps
and Neophron were documented as morphometrics
distribution ranges
and conservation status were reviewed and comprehensively discussed. A total of
29 voucher specimens belong to six species which are conserved in the “Iraq Natural
History Research Center and Museum INHM” as follow: Marsh Harrier Circus aeruginosus
(Linnaeus
1758)
Hen Harrier Circus cyaneus (Linnaeus
1766)
Montagus Harrier Circus
pygargus (Linnaeus
1758)
Pallid Harrier Circus macrourus (Gmelin
1770)
Egyptian
vulture Neophron percnopterus (Linnaeus
1758)
and Griffon vulture Gyps fulfus (Hablitz
1783). The results revealed significant criteria about near threatened NT species IUCN
and Birdlife International listed as Pallid Harrier Circus macrourus
and Endangered
(EN) species as Egyptian vulture Neophron percnopterus globally decreasing population
trend.
