The zeolite's textural properties have a significant effect on zeolite's effectiveness in the different industrial processes. This research aimed to study the textual properties of the NaX and FeX zeolites using the nitrogen adsorption-desorption technique at a constant low temperature. According to the International Union of Pure and Applied Chemistry, the adsorption-desorption isotherm showed that the studied materials were mixed kinds I/II isotherms and H3 type hysteresis. The Brunauer-Emmett-Teller isotherm was the best model to describe the nitrogen adsorption-desorption better than the Langmuir and Freundlich isotherms. The obtained adsorption capacity and Brunauer-Emmett-Teller surface area values for NaX were greater than FeX. Ac

   This work prepared new composite (CuO/NaOH/CW) and compared with another composite (HNO₃/NaOH/CW) from cotton waste, sodium hydroxide, copper sulphate and nitric acid for the treatment of refinery wastewater.  Dry weight analysis confirmed the attachment of 29 and 32 % NPs in the composites of copper oxide and nitric acid, and their observed slow-release behavior contributed to enhanced stability. The accessory of copper oxide to the cotton waste surface fibrils and their deep infiltration into the matrix were obviously established by characterization analysis. The composite material was evaluated for its adsorption and photodegradation capabilities for organic removal from refinery wastewater (RWW). Remarkably, the synt

       Scientists are investigating the efficacy of different biosorbents for promoting economic and environmental viability in purifying contaminants. Among the primary by-products of biodiesel production is waste microalgae biomass, which has the potential to be used as a cheap biosorbent for the treatment of pollution. In the present study, the biomass left over after extracting the chlorella vulgaris was used to test the potential biosorption of CIP from simulated aqueous solutions. Bisorbent's ability was characterized using Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and energy-dispersive X-ray spectroscopy (EDX). Analysis with a Fourier Transform Infrared Spectrometer revealed that C

   The Tigris River in Baghdad is increasingly polluted by industrial and agricultural activities and untreated sewage, posing serious risks to public health and the environment. This pollution degrades water quality through various physical, chemical, and biological contaminants. This research aims to use membrane filtration techniques to treat Tigris River water, improving water quality and ensuring a clean, safe water supply. The study assesses the efficiency of polypropylene (P.P) 1µm, ceramic 0.5µm microfiltration, and polyvinylidene fluoride (PVDF) 500KD ultrafiltration membranes in removing turbidity, total suspended solids (TSS), and E. coli, and their impact on permeate flux. Experiments were conducted at a temperature of 25

Microwave power has a more significant effect on cracking with less energy consumption. The microwave power and the catalysis increase the racking rate and the conversion at lower temperatures.  Accordingly, the generated hot spots in the catalyst offer a suitable condition for cracking (high rate and low temperature). The microwave technique was used to conduct the cracking of heavy naphtha. A set of experiments was done with microwave power (750–1250 W), preheating temperatures (150–250 ˚C), and space velocities (2–6 l/hr) with and without nitrogen injection. The nitrogen injection enhanced the conversion for all situations. The best result has a conversion of 47.37% with nitrogen injection at microwave power of 1250 W, a flow

Animal fats are a good, promising and ethical alternative source for biodiesel production, but they need more complex treatments than vegetable oils. Iraqi butchery plants waste fats (sheep fat) which are suggested as feedstock to produce biodiesel. This type of fat contains a large quantity of free fatty acids (FFAs) (acid number 49.13 mg KOH/g of fat). The direct transesterification of such fats produce high amount of soap instead of desired biodiesel, so a pre-treatment step (to reduce FFAs) is necessary before transesterification. This step was done by esterification of the free fatty acids in the fat by adding ethanol and using 1% acid catalyst (H2SO4) for 30 minutes. The results showed that the acid number of sheep fat after pre-tr

In this work, microbubble dispersed air flotation technique was applied for cadmium ions removal from wastewater aqueous solution. Experiments parameters such as pH (3, 4, 5, and 6), initial Cd(II) ions concentration (40, 80, and 120 mg/l)  contact time( 2, 5, 10 , 15, and 20min), and surfactant (10, 20and 40mg/l) were studied in order to optimize the best conditions .The experimental results indicate that microbubbles were quite effective in removing cadmium ions and the anionic surfactant SDS was found to be more efficient than cationic CTAB in flotation process. 92.3% maximum removal efficiency achieved through 15min at pH 5, SDS surfactant concentration 20mg/l, flow rate250 cm³/min and at 40mg/l Cd(II) ions initial co

Phenol oxidation by Fenton's reagent (H2O2 + Fe+2) in aqueous solution has been studied for the purpose of learning
more about the reactions involved and the extent of the oxidation process, under various operating conditions. An initial
phenol concentration of 100 mg/L was used as representative of a phenolic industrial wastewater. Working temperature
of 25C was tested, and initial pH was set at 5.6 . The H2O2 and the Fe+2 doses were varied in the range of
(H2O2/Fe+2/phenol = 3/0.25/1 to 5/0.5/1). Keeping the stirring speed of 200 rpm.
The results exhibit that the highest phenol conversion (100%) was obtained under (H2O/Fe+2/phenol ratio of 5/0.5/1)
at about 180 min. The study has indicated that Fenton's oxidation i

   For a reservoir with high storage capacity and low ability to produce, the serious problem is the sharp reduction in the recorded well productivity within a short period. One solution to this problem is to create hydraulic fractures that increase formation permeability and keep its production at high rates for a sufficient time. The field under study is the East Baghdad oil field of three formations: Saadi, Tanuma, and Khasib. Knowing the geomechanical behavior of these reservoirs has a critical effect on the success of hydraulic fracturing operations. In this study, rock stress magnitude and direction, rock elasticity, rock strength to fracturing initiation, and all these parameters in addition to petrophysical properties will be u

This study aims to conduct a comprehensive formation evaluation of a pilot area within the Upper Shale Member of the Rumaila Oil Field. This evaluation is an essential step in the full development of the field. The application of well-log data and core analyses can help in obtaining the desired information about the geological characteristics of the formation. The process begins with measuring the formation temperature and water resistance utilizing Schlumberger’s charts and equations. The volume of shale was determined by two different methods, which were then used together to obtain the final shale volume. The porosity was determined using the conventional porosity equations from the porosity logs and the saturation was estimated bas

Prediction of penetration rate (ROP) is important process in optimization of drilling due to its crucial role in lowering drilling operation costs. This process has complex nature due to too many interrelated factors that affected the rate of penetration, which make difficult predicting process. This paper shows a new technique of rate of penetration prediction by using artificial neural network technique. A three layers model composed of two hidden layers and output layer has built by using drilling parameters data extracted from mud logging and wire line log for Alhalfaya oil field. These drilling parameters includes mechanical (WOB, RPM), hydraulic (HIS), and travel transit time (DT). Five data set represented five formations gathered

Catalytic reforming of naphtha occupies an important issue in refineries for obtaining high octane gasoline and aromatic compounds, which are the basic materials of petrochemical industries. In this study, a novel of design parameters for industrial continuous catalytic reforming reactors of naphtha is proposed to increase the aromatics and hydrogen productions. Improving a rigorous mathematical model for industrial catalytic reactors of naphtha is studied here based on industrial data applying a new kinetic and deactivation model. The optimal design variables are obtained utilizing the optimization process in order to build the model with high accuracy and such design parameters are then applied to get the best configuration of this pro

   Drilling operations in Basra's oil fields, particularly targeting the Dammam, Hartha, and Shuaiba formations, are facing significant challenges related to lost circulation. This study investigates the effects of incorporating lost circulation materials (LCMs) into bentonite-based and polymer-based drilling muds. Experiments were carried out using a high-pressure high-temperature filter press to evaluate the rheological properties and filtration performance of the different mud systems prepared using bentonite and polymer mixed with various compositions of additives. The results showed that the incorporation of LCMs increased the plastic viscosity and yield point of the polymer mud by 25-30%, while the impact on the bentonite mud was

In the present work a modification was made on three equations to represent the
experiment data which results for Iraqi petroleum and natural asphalt. The equations
have been developed for estimating the chemical composition and physical properties
of asphalt cement at different temperature and aging time. The standard deviations of
all equations were calculated.
The modified correlation related to the aging time and temperature with penetration
index and durability index of aged petroleum and natural asphalts were developed.
The first equation represents the relationship between the durability index with aging
time and temperature.

log_e(DI)=a₁+0.0123(2log_e T

The objective of the conventional well testing technique is to evaluate well- reservoir interaction through determining the flow capacity and well potential on a short-term basis by relying on the transient pressure response methodology. The well testing analysis is a major input to the reservoir simulation model to validate the near wellbore characteristics and update the variables that are normally function of time such as skin, permeability and productivity multipliers.

Well test analysis models are normally built on analytical approaches with fundamental physical of homogenous media with line source solution. Many developments in the last decade were made to increase the resolution of transient response derivation to meet the

تناول البحث الحالي تحديد المسار التكنولوجي لاسترداد مذيب الزايلين المستخدم في تحضير السبائك البوليمرية نوع (بولي اثيلين-بولي سايلوكسان) باعلى نسبة ممكنة. وتم ذلك من خلال دراسة تاثير المتغيرات الحاكمة باعتماد اسلوبين في الاسترداد وهما الاسترداد بالهواء الحار والاسترداد بالتبريد والترشيح. اظهرت النتائج ان اعتماد اسلوب التبريد والترشيح يعطي نتائج فضل من حيث نسبة الاسترداد والتي بلغت 75% ومن حيث

PC-based controller is an approach to control systems with Real-Time parameters by controlling selected manipulating variable to accomplish the objectives. Shell and tube heat exchanger have been identified as process models that are inherently nonlinear and hard to control due to unavailability of the exact models’ descriptions. PC and analogue input output card will be used as the controller that controls the heat exchanger hot stream to the desired temperature.
The control methodology by using four speed pump as manipulating variable to control the temperature of the hot stream to cool to the desired temperature.
In this work, the dynamics of cross flow shell and tube heat exchanger is modeled from step changes in cold water f

   Linear alkylbenzene sulphonate (LAS), a surfactant frequently incorporated into detergent formulations, typically ends up in wastewater treatment facilities after use. The present study aims to investigate the efficacy of bacteria isolated from Iraqi wastewater in removing LAS. This strain was identified as Pseudomonas aeruginosa by genetic analysis (16S rRNA). Three LAS concentrations (25, 50, and 100 mg/l) were employed in this investigation, along with three temperatures (30, 35, and 40 oC) and pH values (5, 7, 9). The LAS anionic surfactant demonstrated optimal biodegradation by Pseudomonas aeruginosa at a temperature of 30 °C and at pH levels of 7 and 9, with removal percentages of 93.76% and 90.4%, respectively, at a concentr

Single long spiral tube column pressure swing adsorption (PSA) unit, 25 mm diameter, and 6 m length was constructed to study the separation of water from ethanol at azeotropic concentration of 95 wt%. The first three meters of the column length acted as a vaporizer and the remaining length acted as an adsorber filled by commercial 3A zeolite. The effect of pressure, temperature and feed flow rate on the product ethanol purity, process recovery and productivity were studied. The results showed that ethanol purity increased with temperature and pressure and decreased with feed flow rate. The purity decreased with increasing productivity. The purity range was 98.9 % to 99.6 %, the recovery range was 0.82 to 0.92 and the productivity range w

   The identification studies of rock and reservoir characteristics are essential for evaluating the efficiency of a reservoir by analyzing the types of rock and pores. In this study, Nuclear Magnetic Resonance (NMR) for six wells was utilized to identify the rock and reservoir characteristics of the Mishrif formation in the South of the Zubair Field, specifically the Rafdyia and Safwan domes, as well as the west flank. Specific correlations were utilized to describe the classification of rocks, estimate pore throat radius, and recognize possible flow intervals. The results revealed that the Mishrif Formation mainly consists of limestone, dolomite, and shale. The Safwan dome consists mainly of pack-wackestone, wackestone, and mudstone,

   In this study, lead ions were removed from simulated wastewater by batch adsorptive filtration. A three-dimensional printed water filtration was designed using a blender and successfully synthesized from a PLA spool and a 3d printer machine. The filter surface was treated with NaOH solution to hydrolyze the polyester group in PLA. After that, α-Fe₂O₃ was prepared by the coprecipitation method and coated on the filter through doping and drying. α-Fe₂O₃ was characterized by X-ray diffraction (XRD), Energy-dispersive X-ray spectroscopy (EDX), and Brunauer-Emmet-teller (BET). The results successfully indicate the synthesis of α-Fe₂O₃ consisting of 67.3% Fe and 32.7% O<

In this paper activated carbon adsorbents produced from waste tires by chemical activation methods and application of microwave assisted KOH activation. The influence of radiation time, radiation power, and impregnation ratio on the yield and oil removal which is one of the major environmental issues nowadays and considered persistent environmental contaminants and many of them are suspected of being carcinogenic. Based on Box-Wilson central composite design, polynomial models were developed to correlate the process variables to the two responses. From the analysis of variance the significant variables on each response were identified.  Optimum conditions of 4 min radiation time, 700 W radiation power and 0.5 g/g impregnation ratio

The minimization, treatment and disposal of drilling wastes especially oily wastes are important environmental issues.

In this research two fungal isolates named Pleurotus ostreatus and Trichoderma harzianum were chosen carefully f or the purpose of biotreatment of oily drilled cuttings which resulting from  drilling oil wells using oil based muds (OBMs).

A relationship of total petroleum hydrocarbon degradation in oily drilled cuttings with time has been obtained. The results showed that Pleurotus ostreatus and Trichoderma harzianum can be considered hydrocarbon degrading microorganisms and the used biotreatment is cost effective process since most of the materials used in the cultivation and growth of the present f

The special core analysis tests were accomplished on a set of core plugs for Mishrif Formation (mA, mB1, and mB2cde/mC units) in West Qurna/1 oilfield, southern Iraq. Oil relative permeability (K_ro) data and the Corey-type fit of the data as functions of the brine saturation at the core outlet face for individual samples in the water-oil imbibition process to estimate relative permeability measurements by the centrifuge method were utilized. Identical correlations for oil and water relative permeabilities were extracted by steady-state and unsteady-state methods. For the mA samples, the gas-water capillary pressure curves were within a narrow range (almost identical) indicating that mA is a homogeneous unit. Kro curves for thr

The research discussed the possibility of adsorption of Brilliant Blue Dye (BBD) from wastewater using 13X zeolite adsorbent, which is considered a byproduct of the production process of potassium carbonate from Iraqi potash raw materials. The 13X zeolite adsorbent was prepared and characterized by X-ray diffraction that showed a clear match with the standard 13X zeolite. The crystallinity rate was 82.15% and the crystal zeolite size was 5.29 nm. The surface area and pore volume of the obtained 13X zeolite were estimated. The prepared 13X zeolite showed the ability to remove BBD contaminant from wastewater at concentrations 5 to 50 ppm and the removal reached 96.60% at the lower pollutant concentration. Adsorption measurements versus tim

In this study, successive electrocoagulation (EC) and electro-oxidation (EO) processes were used to minimize some of the major pollutants in real wastewater, such as organics (detected by chemical oxygen demand (COD)), and turbidity. The wastewater utilized in the present study was collected from the Midland Refinery Company in Baghdad-Iraq. The performance of the successive batch EC-EO processes was studied by utilizing Graphite and Aluminum (Al) as monopolar anode electrodes and stainless steel (st.st.) as the cathode. The Taguchi experimental design approach was used to attain the best experimental conditions for COD reduction as a major response. Starting from chemical oxygen demand COD of (600 ppm), the effects of current density (C