The petroleum industry faces a significant problem in enhanced oil recovery (EOR) from carbonate reservoirs because of their mostly oil-wet character, which restricts hydrocarbon extraction. To better understand how surfactant-polymer techniques can enhance oil recovery, this study investigates the effectiveness of polyvinyl alcohol (PVA) as a stand-alone agent and the function of ionically modified smart water on carbonate properties. The study focuses on its effect on critical parameters essential for effective oil displacement and recovery, such as wettability alteration, interfacial tension, and surface tension (ST) using different brines (smart water). The ability of the polymer PVA to lower interfacial and surface tensi
... Show MoreNaturally carbonate reservoirs have very low oil recovery efficiency owing to their wettability and tightness of matrix. However, adding surfactant to brine solution can enhance oil recovery by changing the wettability of the carbonate rock surface from oil-wet to water-wet. In the present study, the effects of different brines in the presence of surfactant hexadecyltrimethylammonium bromide (CTAB), on the wettability of carbonate rock were investigated through different characteristics such as surface tension interfacial tension and contact angle. The best concentration of CTAB was investigated at 500 ppm in brine (NaCl) reduced surface tension and interfacial tensions to 42 mN/m and 15 mN/m respectively and prevented reservoir fro
... Show MoreChanging oil-wet surfaces toward higher water wettability is of key importance in subsurface engineering applications. This includes petroleum recovery from fractured limestone reservoirs, which are typically mixed or oil-wet, resulting in poor productivity as conventional waterflooding techniques are inefficient. A wettability change toward more water-wet would significantly improve oil displacement efficiency, and thus productivity. Another area where such a wettability shift would be highly beneficial is carbon geo-sequestration, where compressed CO2 is pumped underground for storage. It has recently been identified that more water-wet formations can store more CO2. We thus examined how silica based nanofluids can induce such a wettabil
... Show MoreNanofluids, liquid suspensions of nanoparticles (NPs) dispersed in deionized (DI) water, brine, or surfactant micelles, have become a promising solution for many industrial applications including enhanced oil recovery (EOR) and carbon geostorage. At ambient conditions, nanoparticles can effectively alter the wettability of the strongly oil-wet rocks to water-wet. However, the reservoir conditions present the greatest challenge for the success of this application at the field scale. In this work, the performance of anionic surfactant-silica nanoparticle formulation on wettability alteration of oil-wet carbonate surface at reservoir conditions was investigated. A high-pressure temperature vessel was used to apply nano-modification of oil-wet
... Show MoreThis work was conducted to study limestone rock wettability alteration to enhance oil recovery by flooding using different Nano silica (NS) sizes suspended in saline water and compared with flooding solution of polyethylene glycol (PEG) polymer and sodium dodecyl sulfate (SDS) surfactant, the stability of nanofluids measured by zeta potential. In the flooding system, the secondary recovery by silica nanofluids (0.01 wt. % NS concentration) achieved an oil recovery of 35vol. % and 26.08 vol. % for 10, 52 nm after primary recovery respectively, while PEG polymer and SDS surfactant achieved oil recovery of 5 vol. % and 10 vol. % only respectively. The stability of pressure difference approved that silica nanoparticle never causes any p
... Show MoreNanofluid treatment of oil reservoirs is being developed to enhance oil recovery and increase residual trapping capacities of CO2 at the reservoir scale. Recent studies have demonstrated good potential for silica nanoparticles for enhanced oil recovery (EOR) at ambient conditions. Nanofluid composition and exposure time have shown significant effects on the efficiency of EOR. However, there is a serious lack of information regarding the influence of temperature on nanofluid performance; thus the effects of temperature, exposure time and particle size on wettability alteration of oil-wet calcite surface were comprehensively investigated; moreover, the stability of the nanofluids was examined. We found that nanofluid treatment is more efficie
... Show MoreThere is a growing imperative to extract oil not only through primary and secondary means but also via tertiary recovery methods to meet the escalating global energy demands. Consequently, Enhanced Oil Recovery (EOR) is slated to increase significance in the oil industry in the coming years. The amalgamation of low salinity water (LSW) with chemicals to augment oil recovery has gained substantial traction in recent years owing to its demonstrated effectiveness. In this study, a systematic investigation utilizing contact angle measurements to elucidate the underlying mechanisms was undertaken. The results reveal that the contact angle (CA) demonstrated the effectiveness of the combined fluid in altering the wettability from oil-
... Show MoreNano materials have a great potential for enhanced oil recovery applications. The present research investigated the effect of nanoparticles on interfacial tension and wettability alteration. The silica oxide nanoparticles with different size 52, 65 and 5nm were used. The wettability alteration was evaluated by dipping the limestone rock in different concentrations of Nano silica (0.01-1wt. %) for a certain silica size suspended in salinity water. Measurements performed in three phase system (oil/water/solid) using pandel droplet and sessile drop method respectively by opitical-tensiometer. Results showed that Nano fluid can significantly reduce contact angle and alterated rock wettabi